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wpcentral 07/16/2019 04:25
Amazon Prime Day has entered day two! Prime Day 2019 for July 15 and 16. That's right, this year's event takes place over two days so we get a full 48 hours of deals — 12 hours more than last year. That 48-hour period will be stacked full of deals that are impossible to sift through on your own, so the Thrifter team will be doing that for you, saving you time and money. Prime Day is set to feature a bunch of deals across every category at Amazon from tech and entertainment to home, garden, fashion, baby, pet, and so much more. There are deals on hardware from some of the biggest manufacturers in every category....
Chiral polyfluoroarene derivatives are an important scaffold in chemistry. An unprecedented enantioselective C–H alkylation of polyfluoroarenes with alkenes is described. The reaction employs bulky chiral N‐heterocyclic carbene (NHC) ligands for nickel catalysts to enable exclusive activation of C–H bonds over C–F bonds and complete endo‐selective C–H annulation and excellent enantioselectivity. A wide variety of chiral fluorotetralins, compounds otherwise difficultly accessed but serve as important bioisosteric analogs of both tetralin and heterocycle units for drug design, are expediently synthesized from easily available substrates. To our knowledge, this is the first example of enantioselective C–H functionalization of polyfluoroarenes.
A chilling pore opening: A cold CO2 stream becomes the secret code for opening a tightly sealed and extra‐framework‐cation‐guarded anionic Mg metal–organic framework (MOF). Once open, various gas molecules can freely dance into or swing out of rigidized channels, until being locked out again. Abstract. We report a new magnesium metal–organic framework (MOF) (CPM‐107) with a special interaction with CO2. CPM‐107 contains Mg2‐acetate chains crosslinked into a 3D net by terephthalate. It has an anionic framework encapsulating ordered extra‐framework cations and solvent molecules. The desolvated form is closed and unresponsive to common gasses, such as N2, H2, and CH4. Yet, with CO2 at 195 K, it abruptly opens and turns into a rigid porous form
IBM - API Connect 07/16/2019 04:20
The Practical Test Pyramid is a common methodology for implementing a testing strategy. In this article we will consider how this applies to an IBM API Connect solution. We will explore the following topics: Practical Test Pyramid Requirements Test types Unit Test Integration Tests Consumer Tests Automated Testing 1. Practical Test Pyramid The practical test pyramid […]
RosBusiness (Russian) 07/16/2019 04:19
Московская городская избирательная комиссия отказала в регистрации 27 кандидатам в депутаты Мосгордумы, сообщили РБК в Мосгоризбиркоме. В качестве кандидатов в депутаты Мосгордумы зарегистрировано ...
Dubai Informer 07/16/2019 04:17
Job title: Waiter Company: Job description: Waiter Job Location : Dubai Good salary and benefits will be offered Requirements : 2- 4 years’ experience… Expected salary: Location: Dubai Job date: Tue, 16 Jul 2019 07:57:36 GMT Apply for the job now! link:

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