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Coordinating solvents are commonly employed as ancillary ligands to stabilize late transition metal complexes and are conventionally considered to have little effect on the reaction products. Our work identifies that the presence of ancillary ligand in Pd‐diimine catalyzed polymerizations of α‐olefins can drastically alter reactivity. The addition of different amounts of acetonitrile allows for switching between distinct reaction modes: isomerization‐polymerization with high branching (0 eq.), regular chain‐walking polymerization (1 eq.), and alkene isomerization with no polymerization (>20 eq.). Optimization of the isomerization reaction mode led to a general set of conditions to switch a wide variety of diimine complexes into efficient al.
The Generated DataBases (GDBs) enumerate billions of possible molecules following simple rules of chemical stability and synthetic feasibility. Exploring the GDBs shows that many chiral, 3D‐shaped ring systems, often containing quaternary centers, have never been exploited for drug design. Herein we show that such ring systems can be useful for medicinal chemistry at the example of the enantioselective synthesis of triquinazine, a novel chiral piperazine analog derived from angular triquinane, and it’s use to design a nanomolar and selective inhibitor of Janus Kinase 1 related to the marketed drug Tofacitinib useful to treat auto‐immune diseases.
GlobeNewswire 09/28/2020 18:26
Í dag samþykktu stjórnir Kviku banka og TM að hefja viðræður um sameiningu félaganna. Forsendur viðræðna byggjast á því að TM verði dótturfélag Kviku banka og að Lykill fjármögnun hf., núverandi dótturfélag TM, sameinist Kviku banka. Þá er gert ráð fyrir að hluthafar í TM fái sem endurgjald fyrir hlutabréf sín í TM 55% hlut í sameinuðu félagi miðað við útgefna hluti félaganna í dag.
ManufacturingTomorrow.com 09/28/2020 18:25
Bally Ribbon Mills announces its newest line of advanced textile products to increase part functionality and utility. As companies demand higher durability and product differentiation, BRM has innovated with its E-WEBBINGS® and TPCM™ thermoplastic materials. BRM's advanced textile products are ideal for electronic transmission data, energy storage, and manufacturing automation.
Financial Post (Canada) 09/28/2020 18:24
The first of a group of three tankers carrying Iranian fuel for gasoline-starved Venezuela entered the waters of the South American nation on Monday, according to Refinitiv Eikon data, in the most recent sign of the countries’ expanding trade. The two OPEC members have increased cooperation this year by exchanging crude, fuel, food, equipment for […]
Solopos.com (Indonesia) 09/28/2020 18:20
Solopos.com, ROMA — Seorang turis asal Irlandia ditangkap usai mengukir inisial namanya di bangunang bersejarah Italia, Colosseum Roma. Turis ini terancam hukuman tahanan maksimal satu tahun penjara dan denda minimal Rp35 juta. Viral Penjual Bubur Kacang Hijau Fasih Bahasa Jepang, Ternyata Belajar dari Sini Dilansir CNN, Senin (28/9/2020), menurut laporan Polisi Carabinieri mengatakan turis dari […]. .
Zero Hedge 09/28/2020 18:20
'Late Night' Biden. Mon, 09/28/2020 - 18:20. What I am wondering about: Why hasn’t US late night TV “comedy” circuit dug into Joe Biden when he provides them with so much material? Am I the only one who’s been puzzled about that? It’s not specifically about Biden, he’s just a tool in a game, for late night comedy, it’s all about Donald Trump, and they ignore that beyond him, there’s a naked bloody battle between two US political parties. But why would comedians want to take sides in that battle? And is doing that a good idea for their careers? I could have opened with: ”Late Night Biden? There’s no such thing, Joe’s fast asleep by then”! But the only people who would say such a thing today are in the Trump camp, not in late night “comedy”. Wh.
GlobeNewswire 09/28/2020 18:20
Today the Board of Directors of Kvika banki and the Board of Directors of TM agreed to commence discussions on the merger of the two companies. Discussions are based on the premises that TM will become Kvika banki‘s subsidiary and that Lykill fjármögnun hf., TM‘s subsidiary, will merge with Kvika banki. It is also expected that TM‘s shareholders will receive a 55% share in the merged company in return for their shares in TM, based on the companies‘ issued share capital today.
Mining News (Africa) 09/28/2020 18:19
By NJ Ayuk Mozambique’s LNG project could be transformational for Mozambique – if Western environmentalists don’t interfere. When Anadarko Petroleum Corp. confirmed last year it would be constructing a $20 billion liquified natural gas (LNG) plant in Mozambique, this was major news. Mozambique’s first onshore LNG plant would be creating tens of thousands of jobs […]. The post first appeared on .
Business Wire 09/28/2020 18:18
CAMBRIDGE, Inglaterra, y RICHARDSON, Texas--(BUSINESS WIRE)--Mavenir, proveedor líder de software de red integral y nativo en la nube para proveedores de servicios de comunicaciones (Communications Service Providers, CSP), anunció hoy que ha adquirido ip.access Ltd., proveedor de soluciones de celdas pequeñas para 2G, 3G, 4G y 5G.

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