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Metallocene catalysis is widely used in transformations of unsaturated organic compounds, including the bulk industrial synthesis of polyolefins. Over the last few decades, the electronic and structural properties of their η 5 ‐coordinated ligands have been modified by introducing electron‐donating, electron‐withdrawing, and sterically hindered substituents to obtain desirable catalytic properties for the metallocenes. An efficient way to design η 5 ‐coordinated ligands is to exploit the annelation of heterocyclic fragments with a cyclopentadiene ring. In the present review, we summarize, systematize, and analyze synthetic approaches to heterocycle‐fused cyclopentadienes suitable for metallocene catalyst preparation. 1 Introduction. 2 Pyridi.
Guardian (United Kingdom) 04/10/2020 09:13
France and Netherlands at odds on finance ministers’ €500bn compromise. France and the Netherlands have openly clashed over the meaning of a which has unlocked a €500bn (£438bn) pandemic rescue package for European economies but left major issues unresolved. Hours after a breakthrough was secured late on Thursday evening to allow immediate support for businesses and healthcare systems, it became clear on Friday that there remained over the longer-term task of rebuilding the European economy.
EAI Daily (India) 04/10/2020 09:12
This post is a part of BioBiz’s Bio-CNG Perspectives. BioBiz, a division of EAI, is a leading market intelligence & strategic consulting firm for the Indian bio-based sectors. This blog post uses the terms bio-CNG and renewable natural gas (RNG) interchangeably. Bio-CNG or bio-compressed natural gas, also known as sustainable natural gas or biomethane, is a biogas which has been upgraded to a […]

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