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Financial Post (Canada) 09/25/2020 02:52
WASHINGTON — The U.S. Justice Department asked a federal judge in San Francisco early on Friday to allow the government to bar Apple Inc and Alphabet Inc’s Google from offering WeChat for download in U.S. app stores pending an appeal. The filing asked U.S. Magistrate Judge Laurel Beeler to put on hold her preliminary injunction […]
Herein we report a mild and diastereoselective access to ketonitrones by reacting easily available aryl acetic acid esters and nitrosoarenes under catalytic loading of 2‐tert‐butylimino‐2‐diethylamino‐1,3‐dimethylperhydro‐1,3,2‐diazaphosphorine (BEMP) at room temperature.
A deoxygenative 1,1‐bis‐trifluoromethylthiolation of readily available aromatic aldehydes with AgSCF3 in the presence of KI and (NH4)2SO4 was established. This reaction delivered a series of bis(trifluoromethylthio)methylarenes in moderate to high yields. The precise control of the generation and decomposition of SCF3 anion is the key to the successful transformation.

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