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Abstract. Fully substituted heterofunctionalized triazoles can be prepared by indirect and direct approaches. The indirect strategies are well‐established but have limitations. Herein, we developed a direct methodology to access fully substituted 5‐thiocyanato‐1,2,3‐triazoles with high regioselectivity from the azide‐internal thiocyanatoalkyne cycloaddition reaction under mild conditions. This is the first time that fully substituted 5‐thiocyanato‐1,2,3‐triazoles have been prepared and the first time an AAC/nucleophilic substitution cascade reaction have been used to generate various fully substituted triazolyl−organosulfurs, such as 5‐sulfur‐triazoles and 5‐sulfinylcyanato‐triazoles from common internal thiocyanatoalkyne precursors. This ap.
მსახიობი და ტელეწამყვანი გიორგი გასვიანი რამდენიმე წელია რაც ტელეეკრანებზე გამოჩნდა და საკუთარი იმიჯი თავად შექმნა. სოხუმიდან დევნილი ჟურნალისტი თეატრის მსახიობობას და გადაცემა „სიცრუის დეტექტორის“ წამყვანობას თანაბრად წარმატებით ითავსებს. ვინ გააკრიტიკა გიორგი გასვიანის დამატყვევებელი მზერა?


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