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Your search is now limited to «Silicones» expert search. 09/18/2020 03:00
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Molecular silicon polycations of the types R 2 Si 2+ and RSi 3+ (R = H, organic groups) are elusive Lewis superacids and currently unknown in the condensed phase. Here, we report the synthesis of a series of isolable terpyridine‐stabilized R 2 Si 2+ and RSi 3+ complexes, [R 2 Si(terpy)] 2+ (R = Ph 1 2+ ; R 2 = C 12 H 8 2 2+ , (CH 2 ) 3 3 2+ ) and [RSi(terpy)] 3+ (R = Ph 4 3+ , cyclohexyl 5 3+ , m‐xylyl 6 3+ ), in form of their triflate salts. The stabilization of the latter is achieved through higher coordination and to the expense of reduced fluoride ion affinities, but a significant level of Lewis superacidity is nonetheless retained as verified by theory and experiment. The complexes activate C(sp 3 )–F bonds, as showcased by stoichiomet.
New Statesman (UK) 09/16/2020 07:31
Dominic Cummings wants to create a British tech company that could rival the Silicon Valley giants. So why is the government turning downing the chance to rehome a firm that does just that? In early September, Dominic Cummings revealed to colleagues that he was exploring plans to scale up Britain's technology industry. "[We are looking at] ways we can build [$1trn] tech companies", the Downing Street adviser wrote in an email, as Business Insider . The government, according to the Times , is so committed to investing in the tech sector that it might be willing to in order to unshackle itself from EU state aid rules. Why, then, less than a fortnight after Cummings' ambitious missive, is the government now passing up the chance to rehome a co. 09/16/2020 03:29
Pune, Maharashtra, India, September 16 2020 (Wiredrelease) MarketResearch.Biz –:The recent report posted via MarketResearch.Biz on Suprapubic Catheter market offers critical market insights in conjunction with targeted segmentation evaluation. The report examines key using elements which might be anticipated to drive the increase of the market. Global Suprapubic Catheter Market Research Report offers crucial data on numerous market situations, for example, ability improvement elements, elemen...


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