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Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02106J, Paper. Guirong You, Dan Xi, Jian Sun, Liqiang Hao, Chengcai Xia A convenient and straightforward three-component transformation of quinoline N-oxides, sodium metabisulfite and aryldiazonium tetrafluoroborates has been developed, providing the target products in moderate to good yields. Compare with previous works,... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01949A, Paper. Angelina V. Kazakova, Alexander S. Konev, Ivan Zorin, Igor S. Poshekhonov, Viktor Korzhikov-Vlakh, Alexander F. Khlebnikov Diastereoselective synthesis of water-soluble fullerene compound bearing pharmacophore fulleropyrrolidine-2’,5’-dicarboxalate unit is reported. The stereocontrol of the product configuration is achieved through stereospecificity of two consequtive concerted reactions: electrocyclic aziridine ring... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02119A, Paper. Nico Santschi, Benson Jelier, Samuel Stähelin, Thomas Nauser The oxidative activation of the perfluorinated analogue of dimethyl sulfoxide, DMSO-F 6 , by hydroxyl radicals efficiently produces trifluoromethyl radicals based on pulse radiolysis, laboratory scale experiments, and comparison of rates of... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02096A, Communication. Fouzia Ouadah Bensalah, Abed Bil, Karlo Wittine, Salima Bellahouel, David Lesur, Dean Markovic, Sylvain LACLEF The transamidation reaction of unprotected glycosyl carboxamides is described. This new method is green and atom efficient with good to high yields. Notably, the conditions do not require neither solvent... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01999E, Paper. Sandip Guchhait, Rajib Kumar Goswami Stereoselective construction of acyclic skeleton of aglycon of polyene macrolactam macrotermycin C has been achieved first time using a convergent strategy. The important features of this synthetic study include Evans... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Advance Article DOI : 10.1039/C9OB01972C, Communication. Maddali L. N. Rao, Boddu S. Ramakrishna, Sachchida Nand A Rh-catalyzed domino synthesis of 4-hydroxy-3-methylcoumarins via branch-selective hydroacylation of acrylates and acrylamides using salicylaldehydes is described. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02023C, Paper. Jia-Qi Shang, Xiang-Xiang Wang, Yangchun Xin, Yi Li, Bin Zhou, Ya-Min Li A oxidative decarboxylative cascade cyclization of α-keto acids with 2-cyano-3-arylaniline derived acrylamides was developed. This cascade reaction exhibits a broad substrate scope, and provides an efficient access to carbonyl-containing pyrido[4,3,2-gh]phenanthridines.... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01762C, Paper. Arun L Patel, Heta Patel, Viraj Bhanvadia, Hemant Mande, Sanjio S Zade A convenient and effective synthetic approach for the benzochalcogendiazole-based small molecules has been achieved using polyaniline (PANI)-anchored palladium as a heterogeneous catalyst. The photophysical properties of the synthesized benzochalcogendiazole-based small... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02124H, Paper. Jorge García-Lacuna, Gema Domínguez, Jaime Blanco-Urgoiti, Javier Perez-Castells A new synthesis of treprostinil is described using a plug flow reactor in two of the key steps. First, a Claisen rearrangement reaction is described in scaled flow at multigram... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02014D, Communication. Bing-Ke Ning, Hao-Jie Rong, Cui-Feng Yang, Tao Chen, Ze-Gang Xu, Tian-Duo Su, Yong-Qiang Wang Herein we report that iodine-catalyzed guanylation of primary amines can be accomplished with N,N′-di-Boc-thiourea and TBHP to afford the corresponding guanidines in 40–99% yields. Oxidation of the HI byproduct by... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01976F, Paper. Soumya Dutta, Amit Saha An efficient method for synthesis of unsymmetrical diaryl sulfides has been developed by the C-S cross coupling of aryldithiocarbamates and aryldiazonium salts in presence of CuI-2,2′-bipyridine and Zn. Aryldithiocarbamate compounds... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02067E, Paper. Min Lu, Hong Li, Chuncheng Zou, Jianchang Li, Chengyu Liu, Maolin Sun, Yueyue Ma, Ruihua Cheng, Jinxing Ye The chiral primary amine catalyzed asymmetric Michael reaction of thiazolones and α,β-unsaturated ketones was reported. Two different optimal catalytic systems were obtained responding to cyclic and linear α,β-unsaturated ketones. By... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01781J, Paper. Open Access. This article is licensed under a. Fareeda Barzak, Stefan Harjes, Maksim V. Kvach, Harikrishnan Mohana Kurup, Geoffrey B. Jameson, Vyacheslav Filichev, Elena Harjes To restrict pathogens, in a normal human cell, APOBEC3 enzymes mutate cytosine to uracil in foreign single-stranded DNAs. However, in cancer cells, APOBEC3B (one of seven APOBEC3 enzymes) has been... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01700C, Paper. Arun Sharma, Vivek Sharma, Swapandeep Singh Chimni An efficient asymmetric organocatalytic conjugate addition reaction of pyrazolin-5-ones with arylomethylidene malonates has been successfully developed with the help of bifunctional Cinchona derived thiourea organocatalyst. The protocol provides straightforward access... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01900F, Paper. Satyanarayana Yennam, Nagaraju Payili, R. Santhosh Reddy, Anjaiah Aitha, Anji Karun Mutha, Gangu Naidu Challa A novel and unexpected aryne insertion cascade reaction on 2-arylidene-1,3-indandiones via conjugate addition of fluoride followed by formal C−C insertion is developed to afford dibenzo[a,d]cycloheptanoid derivatives in good yields with... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB02128K, Communication. Bernard Mark Heron, Stuart Aiken, Christopher Gabbutt, Craig Rice, Dimitrios Zonidis 1,2-Oxathiine 2,2-dioxides have been obtained from their respective 3,4-dihydro-4-dimethylamino precursors, for the first time, by a mild Cope elimination of the 4-dimethylamino function. The application of the 1,2-oxathiine 2,2-dioxide scaffold... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01796H, Paper. Jason Robert Zbieg, Jun Li, Xiaojing Wang, Jun Liang, Daniel F Ortwine, Antonio DiPasquale, Yanzhou Liu, Lennon Shao-Xiong Luo, Michael John Lambrecht Nucleophilic addition of Grignard reagents to tetrahydro-β-carboline (THC) N-sulfonyl N,S-acetal generates exclusively cis-1,3-disubstituted THCs with a unique 1,3-diaxial conformation. The stereochemical relationship of the 1,3-substituents was confirmed by 2-dimensional NMR... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01855G, Paper. Le Fang, Giuseppe Trigiante, Rachel Crespo-Otero, Mike Philpott, Christopher Raymond Jones, Michael Watkinson Zn 2+ is involved in a number of biological processes and its wide-ranging roles at the subcellular level, especially in specific organelles, have not yet been fully established due to a... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01814J, Communication. Rebecca Re, Johanna Proessdorf, James J LaClair, Maeva Subileau, Michael Burkart Epoxidation chemistry often suffers from the challenging handling of peracids and thus requires in situ preparation. Here, we describe a two-phase enzymatic system that allows the effective generation of peracids... The content of this RSS Feed © The Royal Society of Chemistry.
Org. Biomol. Chem. , 2019, Accepted Manuscript DOI : 10.1039/C9OB01816F, Paper. Dongliang Liu, Tiju Thomas, Hong Gong, Fei Li, Qiang Li, Lijuan Song, Tamil Azhagan, Heng Jiang, Minghui Yang The reaction of β-hydroxyethylation is essential to the current practice of organic chemistry. Here, we proposed a new and green route to synthesize 2-hydroxyethyl n -alkyl sulfide with n -alkyl mercaptan and... The content of this RSS Feed © The Royal Society of Chemistry.

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