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The ability of HW/CA pairs to assemble NCTs both at elevated temperatures and in the presence of polar solvents capable of disrupting hydrogen bonding demonstrates that increasing the binding strength of NCT supramolecular bonding groups increases the compatibility of the system with more challenging assembly environments.
The molecular-type properties and high stability of atomically precise monolayer-protected gold nanoclusters in the ultrasmall size regime (<2 nm) render them prominent nanomaterials for structure–property studies(1,2) with applications in chemical sensing,(3,4) catalysis,(5,6) nanomedicine(7−9) and optical imaging.

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