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The asymmetric [2+2+2] cycloaddition reactions of 1,6‐enynes and oxabenzonorbornadienes was accomplished by using the complex of [Rh(COD) 2 ]BF 4 and ( R )‐Xyl‐P‐Phos as chiral catalyst. A range of 1,6‐enynes and oxabenzonorbornadienes were well tolerated in the cycloaddition reaction, which afforded various polycyclic products with asymmetric quaternary carbon centers generally in excellent enantioselectivities.
The Conversation 05/26/2019 07:14
Scott Morrison’s new ministry mixes stability with dashes of innovation, box ticking, and the rewarding of friends. The Prime Minister has maintained his record number of women (seven) in cabinet, and created a new entry to the history books by appointing the first indigenous cabinet minister, Ken Wyatt, who will become minister for indigenous Australians. Let’s hope this is not a poisoned chalice for Wyatt, who previously held aged care and indigenous health in the outer ministry.
RosBusiness (Russian) 05/26/2019 07:06
Стремление новой украинской власти усилить антироссийские санкции может привести к неблагоприятным для Украины последствиям. Об этом РБК заявил первый зампредседателя комитета Совета Федерации по ... (UK) 05/26/2019 07:05
The Conservative Party has seen an increase in tens of thousands of new members who have joined ahead of the election to choose a new party leader. The Tories have gained 36,000 paid-up members, which sources told The Telegraph is down to a recruitment drive led by party chairman Brandon Lewis. The party now have […]. The post Tory membership increases to 160,000 ahead of leadership election appeared first on .

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