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Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02414J, Edge Article. Open Access. This article is licensed under a. Madhumita Rano, Sumanta Kr Ghosh, Debashree Ghosh Combining the roles of spin frustration and geometry of odd and even numbered rings in polyaromatic hydrocarbons (PAHs), we design small molecules that show exceedingly small singlet-triplet gaps and stable... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02543J, Edge Article. Open Access. This article is licensed under a. Dmitry Tsvelikhovsky, Yelena Mostinski, David Lankri, Yana Konovalov, Riva Nataf A new single-step proline-potassium acetate promoted reductive dehydroxylation of α-ketols is reported. We introduce the unexplored reactivity of proline and, for the first time, reveal its ability to function as... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03081F, Edge Article. Open Access. This article is licensed under a. Qiu-Chao Mu, Yi-Xue Nie, Xing-Feng Bai, Jing Chen, Lei Yang, Zheng Xu, Li Li, Chungu Xia, Li-Wen Xu A novel Pd/Cu-cocatalyzed carbonylative cyclizations by C–H activation and N-dealkylative C–N bond activation has been developed for the chemoselective construction of synthetically useful heterocycles. The N,N-dimethylamine group on o-indoly-N,N-dimethylarylamines was... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Advance Article DOI : 10.1039/C9SC03016F, Edge Article. Open Access. This article is licensed under a. Chuanlong Zang, Huawei Wang, Tiantian Li, Yingqian Zhang, Jiahui Li, Mengdi Shang, Juanjuan Du, Zhen Xi, Chuanzheng Zhou Photoirradiation of the PC4AP linker generates an active intermediate that reacts intramolecularly with a primary amine on the carrier peptide/protein, leading to rapid release of the drug without generating any toxic side products. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02835H, Edge Article. Open Access. This article is licensed under a. Jonathan Shikora, Chanchamnan Um, Zainab Khoder, Sherry Chemler Saturated heterocycles are important components of many bioactive compounds. The method disclosed herein enables a general route to a range of 5-, 6- and 7-membered oxygen and nitrogen heterocycles by... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03247A, Edge Article. Open Access. This article is licensed under a. Sandip V Mulay, Or Dishi, Yuan Fang, Muhammad Rizwan Niazi, Linda JW Shimon, Dmitrii Perepichka, Ori Gidron We report the first π-conjugated macrocyclic system with an oligofuran backbone. The calculated HOMO–LUMO gap is similar to that of the corresponding linear polymer, indicating a remarkable electron delocalization. The... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02735A, Edge Article. Open Access. This article is licensed under a. Michael Böhme, Winfried Plass Magnetic properties of coordination polymers like single-chain magnets (SCMs) are based on magnetic domains, which are formed due to magnetic exchange between neighboring anisotropic spin centers. However, the computational restrictions... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03701B, Edge Article. Open Access. This article is licensed under a. Chengyuan Liu, Jia Li, Hao Chen, Richard N. Zare Dramatically higher rates for a variety of chemical reactions have been reported in microdroplets compared with those in the liquid bulk phase. However, the scale-up of microdroplet chemical synthesis has... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Advance Article DOI : 10.1039/C9SC03368H, Minireview. Open Access. This article is licensed under a. Eunha Kim, Heebeom Koo Copper-free click chemistry has resulted in a change of paradigm, showing that artificial chemical reactions can occur on cell surfaces, in cell cytosol, or within the body. It has emerged as a valuable tool in biomedical fields. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02227A, Edge Article. Open Access. This article is licensed under a. Bojan Ambrozic, Anze Prasnikar, Nejc Hodnik, Nina Kostevšek, Blaž Likozar, Kristina Žužek Rožman, Sašo Šturm With Liquid-Cell Transmission Electron Microscopy (LCTEM) we can observe the kinetic processes taking place in nanoscale materials that are in a solvated environment. However, the beam-driven solvent radiolysis, which results... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Advance Article DOI : 10.1039/C9SC03560E, Edge Article. Open Access. This article is licensed under a. Daniele Canestrari, Caterina Cioffi, Ilaria Biancofiore, Stefano Lancianesi, Lorenza Ghisu, Manuel Ruether, John O'Brien, Mauro F. A. Adamo, Hasim Ibrahim Molecular bromine is shown to stereoselectively brominate readily available alkyl phenyl sulphides under exceptionally mild reaction conditions. To cite this article before page numbers are assigned, use the DOI form of citation above. The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03359A, Minireview. Open Access. This article is licensed under a. Lena Pitzer, J. Luca Schwarz, Frank Glorius The concept of reductive radical-polar crossover (RRPCO) reactions is recently emerging as a valuable and powerful tool to overcome limitations of both radical and traditional polar chemistry. Especially in case... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03565F, Edge Article. Open Access. This article is licensed under a. Sebastian Ullrich, Borislav Kovačević, Björn Koch, Klaus Harms, Jörg Sundermeyer A new generation of carbodiphosphoranes (CDPs), incorporating pyrrolidine, tetramethylguanidine, or hexamethyl-phosphazene as substituents is introduced as the up to date most powerful class of non-ionic carbon superbases on the basicity... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03324F, Edge Article. Open Access. This article is licensed under a. Lorenz Schiegerl, Antti J Karttunen, Wilhelm Klein, Thomas F Fässler Unsaturated silicon clusters with only partial substitution, and thus, “naked” Si atoms are well studied species as they are proposed intermediates in gas-phase deposition processes. Although a remarkable number of... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03338F, Edge Article. Open Access. This article is licensed under a. Ka Yan Tong, Jia Zhao, Chun-Wai Tse, Pui-Ki Wan, Jianhui Rong, Ho Yu Au-Yeung We report the development of a new triggered-release system for selective detection of catecholamines in biological samples including living cells. Catecholamines are a class of tightly regulated hormones and neurotransmitters... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03479J, Edge Article. Open Access. This article is licensed under a. Sahil Arora, Juntian Zhang, Vedamayee Pogula, T. R. Hoye Abstract: We report here various pathways by which six-membered N–heteroaromatic compounds react with benzynes that are generated by the HDDA reaction. The initially formed 1,3-zwitterionic species a) can collapse intramolecularly... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02357G, Edge Article. Open Access. This article is licensed under a. Bram Teunissen, Tim T.F.E. Paffen, Ivo A.W. Filot, Menno M.D. Lanting, Tom F. A. de Greef, Roy J.C. van der Haas, E. W. Meijer The adaptivity of biological reaction networks largely arises through non-covalent regulation of catalysts’ activity. Such type of catalyst control is still nascent in synthetic chemical networks and thereby hampers their... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03088C, Edge Article. Open Access. This article is licensed under a. Zhe Zhang, Xiansong Shi, Rui Wang, Ankang Xiao, Yong Wang Polyamide-based thin-film composite nanofiltration membranes are widely used for potable water decontamination, brackish water desalination and wastewater reutilization. However, enhancing water permeance of the polyamide layer within the thin-film composite... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC02804H, Edge Article. Open Access. This article is licensed under a. Hui Wang, Wei Zhao, Cong-Hui Xu, Hong-Yuan Chen, Jing-Juan Xu Plasmonic photocatalysts have opened up a new direction in utilization of visible light and promoting the photocatalytic efficiency. An electrochemical deposition method is reported to synthesis metal@semiconductor (M@SC) core-shell nanocrystals.... The content of this RSS Feed © The Royal Society of Chemistry.
Chem. Sci. , 2019, Accepted Manuscript DOI : 10.1039/C9SC03033F, Perspective. Open Access. This article is licensed under a. Franck Le Vaillant, Jerome Waser The alkynylation of radical intermediates has been known since a long time, but had not been broadly applied in synthetic chemistry, in contrast to the alkynylation of either electrophiles or... The content of this RSS Feed © The Royal Society of Chemistry.

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