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Herein we present a new kind of elastic metal‐organic materials (MOMs) that are capable of multiple stimuli‐responsiveness based on dual stress and thermally responsive triple‐helix coordination polymers. The strong metal‐coordination linkage in combination with the flexibility of organic linkers in these MOMs, rather than the ‘4 Å’ stacking interactions observed in organic crystals, renders the helical chain to be act like a molecular spring and thus accounts for their intriguing macroscopic elasticity. Moreover, the thermosalient effect of elastic MOMs is reported for the first time here. Crystal structure analyses at different temperatures reveal that this thermo‐responsiveness is achieved through adaptive regulation of the triple‐helix
FeedNavigator (EU) 05/25/2020 07:37
The objective of this study was to investigate the effects of hydrated calcium silicate filler (hCS) on resin-based pit and fissure sealants’ acid neutralization, calcium ion release, and mechanical and physical properties. To produce the hCS filler, Portland cement (CS) was mixed with distilled water and ground into fine particles. The particles were then mixed with silanized glass filler and added to a photo-activated resin matrix. To evaluate the acid neutralization and calcium ion release properties, the specimens were immersed in a pH 4.0 lactic acid solution and distilled water for 28 days. Also, the flexural strength, depth of cure, water sorption, and solubility were tested. All of the groups containing hCS and CS required less than.

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